Tightly clutching his Gibson guitar, Mafuyu Satou steps out of his dark apartment to begin another day of his high school life. While taking a nap in a quiet spot on the gymnasium staircase, he has a chance encounter with fellow student Ritsuka Uenoyama, who berates him for letting his guitar's strings rust and break. Noticing Uenoyama's knowledge of the instrument, Satou pleads for him to fix it and to teach him how to play. Uenoyama eventually agrees and invites him to sit in on a jam session with his two band mates: bassist Haruki Nakayama and drummer Akihiko Kaji. Satou's voice is strikingly beautiful, filling Uenoyama with the determination to make Satou the lead singer of the band. Though reticent at first, Satou takes the offer after an emotional meeting with an old friend. With the support of his new friends, Satou must not only learn how to play guitar, but also come to terms with the mysterious circumstances that led him to be its owner.

Following a prank pulled by his perverse friends, Junichi Hashiba asks a gal out in an attempt to change the fact that he's a hopeless virgin. Yukana Yame, the girl in question, is disgusted by Junichi's groveling. However, through a series of teasing remarks, she soon finds herself bonding with him and ultimately accepting Junichi's confession, much to his surprise. Hajimete no Gal follows Junichi as he overcomes his lack of self-confidence and suppresses his sexual urges, all while thrust into a whole new school life full of lively girls and unpredictable mayhem.

The famous Seven Mysteries that every school seems to have are a staple of Japanese urban legends. One of the most well-known of these tales is that of Hanako-san: the ghost of a young girl who haunts the school's bathrooms. Kamome Academy has its own version of Hanako-san's legend. Rumors claim that if one successfully manages to summon Hanako-san, she will grant her summoner any wish. Lured by the gossip, many people have tried to call upon her, yet every attempt has failed. However, when Nene Yashiro, a girl hoping for romantic fortune, dares to summon Hanako-san, she discovers that the rumored girl is actually a boy! After a series of unfortunate events involving Yashiro's romantic desires, she is unwillingly entangled in the world of the supernatural, becoming Hanako-kun's assistant. Soon, she finds out about Hanako-kun's lesser-known duty: maintaining the fragile balance between mortals and apparitions.

Love is unusual for Risa Koizumi and Atsushi Ootani, who are both striving to find their ideal partner in high school—172 cm tall Koizumi is much taller than the average girl, and Ootani is much shorter than the average guy at 156 cm. To add to their plights, their crushes fall in love with each other, leaving Koizumi and Ootani comically flustered and heartbroken. To make matters worse, they're even labeled as a comedy duo by their homeroom teacher due to their personalities and the stark difference in their heights, and their classmates even think of their arguments as sketches. Lovely★Complex follows Koizumi and Ootani as they encourage each other in finding love and become close friends. Apart from their ridiculous antics, they soon find out an unexpected similarity in their music and fashion tastes. Maybe they possess a chemistry yet unknown, but could love ever bloom between the mismatched pair?